By Alan S. Tracey
The 1st entire source at the chemistry of vanadium, Vanadium: Chemistry, Biochemistry, Pharmacology, and useful functions has developed from over 1 / 4 century of analysis that targeting delineating the aqueous coordination reactions that represent the vanadium(V) oxidation country. The authors distill info on organic tactics had to comprehend vanadium results in organic platforms and make this knowledge available to a variety of readers, together with chemists with out wide organic education.
Building a hierarchy of complexity, the ebook offers a dialogue of a few simple rules of 51V NMR spectroscopy by way of an outline of the self-condensation reactions of vanadate itself. The authors delineate reactions with basic monodentate ligands after which continue to extra complex structures corresponding to diols, a-hydroxy acids, amino acids, peptides, to call quite a few. They revisit elements of this series later, yet first spotlight the impact the digital homes of ligands have on coordination and reactivity. They then examine and distinction the impacts of ligands, fairly these of hydrogen peroxide and hydroxylamine, on heteroligand reactivity.
The e-book comprises insurance of vanadium-dependent haloperoxidases and version platforms, vanadium within the surroundings, and technological functions. It additionally in short covers the catalytic reactions of peroxovanadate and haloperoxidase version compounds. It incorporates a dialogue of the vanadium haloperoxidases and the organic and biochemical actions of vanadium(V) together with capability pharmacological functions. The final chapters step open air those limitations through introducing a few facets of the way forward for vanadium in nanotechnology, the recyclable redox battery, and the lithium/silver vanadium oxide battery.
Primary assets documented after every one bankruptcy reduce the necessity to seek the literature, eighty illustrations offer structural info, response schemes, spectra, speciation diagrams, and biochemical schemes, and 22 tables current special info with references to basic resources. choked with present and authoritative details, the e-book covers chemistry and bioinorganic vanadium chemistry in a huge and systematic demeanour that engenders entire figuring out.
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Extra info for Vanadium: Chemistry, Biochemistry, Pharmacology and Practical Applications
1994. Speciation in vanadium bioinorganic systems. 1. A potentiometric and 51V NMR study of aqueous equilibria in the H+-vanadate(V)-L-α-alanyl-L-histidine system. Angew. , Int. Ed. Engl. 48:878–885. 1 ALCOHOLS AND PHENOLS Monomeric vanadate reacts rapidly and reversibly with alcohols and phenols, with reaction occurring within a few milliseconds at room temperature. The products correspond to alkoxovanadate derivatives, the mono- and diesters. The criterion is that the vanadate is protonated so that an OH can be replaced by OR or OAr with release of water.
H. P. M. Miller. 1993. Vanadium(V)-protein model studies: Solid-state and solution structure. J. Am. Chem. Soc. 115:6769–6776. 49. W. 1995. Thermochemistry of vanadium(V+) in aqueous solutions. J. Chem. Eng. Data 40:1276–1280. fm Page 30 Friday, February 16, 2007 3:24 PM 30 Vanadium: Chemistry, Biochemistry, Pharmacology and Practical Applications 50. G. Baro, and L. Pettersson. 1996. Speciation in vanadium bioinorganic systems. 2. An NMR, ESR, and potentiometric study of the aqueous H+vanadate-maltol system.
13. Galeffi, B. S. Tracey. 1989. 51-V NMR investigation of the interactions of vanadate with hydroxypyridines and pyridine carboxylates in aqueous solution. Inorg. Chem. 28:1726–1734. 14. C. Crans, and L. Pettersson. 1997. Speciation in vanadium bioinorganic systems. 4. Interactions between vanadate, adenosine and imidazole—an aqueous potentiometric and 51V NMR study. J. Am. Chem. Soc. 119:7005–7012. 15. S. M. Parkinson. 1986. Vanadium(V) oxyanions: The interaction of vanadate with pyrophosphate, phosphate and arsenate.